I also use plastic wrap as a perfect release on positive forms.
I stopped using vaseline years ago because of it's insidious infiltration into paper, the risk of bad paint adhesion, and oil spots showing up through the paint overtime.
For plaster negative molds, I use strips of all-purpose office paper, very wet, no glue. The paper must be soaked in water, and kept wet while you work, with a spray bottle of water.
When I have covered the entire mold (from edges into th very depths), I brush a diluted layer of white glue with a soft brush, and let dry. This is not only a clean release agent, it also becomes part of your mask. When dry and removed from mold, I brush the same diluted mix of glue on top of the mask, to paste down the overlaps.
I learned that from a friend who has the book from maskmaker Agostino Dessi. It is more of a beautiful photo album, with a brief description of the process. While the method seemed very quickly explained, my own previous failed experiments provided me with the clues I needed to understand the text.
I guess this method could be used over a positive form as well...
Have fun.!